The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Peroxy radicals / Alkylperoxy+Cl / CCl3O2 / Russell(1990)_296-460K_220-280nm(resc)

DATAFILE: CCl3O2_Russell(1990)_296-460K_220-280nm(resc).txt
NAME: trichloromethylperoxy radical
FORMULA: CCl3O2
AUTHOR(YEAR): Russell(1990)
T: 296-460K
λ: 220-280nm(resc)
BIBLIOGRAPHY: J.J. Russell, J.A. Seetula, D. Gutman, F. Danis, F. Caralp, P.D. Lightfoot, R. Lesclaux, C.F. Melius, and S.M. Senkan, "Kinetics and thermochemistry of the equilibrium CCl3 + O2 ↔ CCl3O2", J. Phys. Chem. 94, 3277-3283 (1990); DOI: 10.1021/j100371a012
COMMENTS: Flash photolysis of molecular chlorine in the presence of chloroform and an excess of O2

The data have been rescaled by

V. Catoire, R. Lesclaux, W.F. Schneider, and T.J. Wallington, "Kinetics and mechanism of the self-reactions of CCl3O2 and CHCl2O2 radicals and their reactions with HO2," J. Phys. Chem. 100, 14356-14371 (1996); DOI: 10.1021/jp960572z,

according to the revised absorption cross sections of HO2 derived by

P.D. Lightfoot, R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, "Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry," Atmos. Environ. 26A, 1805-1961 (1992; DOI: 10.1016/0960-1686(92)90423-I

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